The heat capacity is defined by .
It allows to calculate the heat energy which is needed to produce an increase in temperature of a
material. To be independent of the special system, we define a specific heat capacity by dividing with the
mass or the number of atoms (mols) of our sample. Most important is the knowledge of the
thermodynamic contact of the system. If, e.g., the pressure is constant, so a fraction of the
heat energy does not increase the temperature of the system but increases the volume of
the system. Therefor the specific heat capacity of a gas is much higher at constant pressure
() in comparison to
constant volume ().
Starting with the first axioms of thermodynamics
|
| (3.1) |
and taking
|
| (3.2) |
we get
|
| (3.3) |
A main point for the calculation of the specific heat capacity is therefor the calculation of the inner energy.