Introductory Remarks
In this subchapter we will look at some junctions in a cursory manner with the goal to get a basic understanding for current flow and the driving forces behind it.  
We will see that it is possible (with only a little cutting of corners) to come to a complete quantitative description of the current  voltage relationship of a pnjunction; even including the (usually omitted) generation current part, without doing a lot of math.  
We will do this in three steps: First we look at a hypothetical junction, than at the classical pnjunction, than at a real pnjunction with recombinationgeneration currents in the space charge region.  
But don't deceive yourself! These are difficult subjects, even if they are made to look relatively easy here.  
We will delve somewhat deeper into these subjects later. However, within the scope of this course, there will not be enough time to go into junction theory thoroughly and in depth.  
Here we only attempt to give enough background knowledge, so you can understand the rigid treatment of device physics that can be found in many books.  
Equilibrium Between a Semiconductor and its Surface as a Model
First, we must realize that the surface is a defect  there is no periodic lattice anymore; the bonds of the surface atoms have some other arrangements than the bonds in the bulk.  
The dispersion relation of electrons in the twodimensional surface "crystal" thus must be expected to be different from that of the bulk.  
In the simplest approximation conceivable, we may picture the surface with the same band diagram as the bulk (but in only two spacial dimensions), but with plenty of additional states in the band gap.  
We have then the following representation:  


The surface introduces some unspecified states in the band gap of a ntype semiconductor (shown here arbitrarily as acceptor states). The Fermi energy will adjust itself as shown: Since states in the bandgap are available that are lower than the donor states (not shown for graphic simplicity) electrons will move to these states  the Fermi energy must come down.  
We will now consider what is going to happen if we bring the bulk and the surface in close contact  i.e. if we look at the real situation. 
Shown here are three graphical representations of the (fictitious) process upon contact.  

Upon contact, the electrons from the conduction band of the bulk will flow to the still empty states of the surface. This will put an additional negative charge at the surface.  

In response to the negative surface charge, the electrostatic potential at the surface goes up and extends (decreasingly) into the bulk  we have a builtin potential V(x). The simplest way to visualize the band bending going with this potential is to remember that the electrons from the bulk are repelled by the negative surface charge; work is needed to move them to the surface; this is an uphill process  

As long as energy can be gained by moving electrons from the bulk to the surface, the process will continue. Equilibrium is reached as soon as as it makes no difference any more if one more electron is in the bulk or on the surface, i.e. if we change the electron count by Dn_{e}. This means that (¶G/¶n_{e}) · Dn_{e}(bulk) = chemical potential µ = Fermi energy E_{F} in the bulk = (¶G/¶n_{e}) · Dn_{e}(surface), or in other words:  


This is a crucial point; let's make it again:  


If you are not too sure about this, read up about the concept of the chemical potential in the basic module.  
This automatically leads to an imbalance of charge, we now have local violations of charge equilibrium.  
The area with the band bending will not contain free electrons, but still the ionized positively charged donor atoms, it thus contains charges in space and is called a space charge region (SCR).  
The SCR also contains an electrical field E which is given directly (via the Poisson equation) by the derivative of the electrostatic potential V by E =  V, or for the onedimensional case, E_{x} =  dV/dx.  
The Space Charge Region  
The easiest way to think about this electrical field is to consider the field lines, which must start at a positive charge and end at a negative charge.  
The negative charges must be the surplus electrons sitting in the surface states (and thus also in real space at the surface), the positive charges must be the ionized donor atoms in the bulk.  
This view immediately leads to a "quick and dirty" formula for the width d of the space charge region: We consider the capacitance C_{SCR} of the SCR.  
Since the positive charges are spread homogeneously through the volume of the SCR, we approximate the capacity of the SCR by a plate capacitor with half the distance between the plates, d_{cap} = d/2. In other words, we sort of put all the positive charge on on fictitious plate at half the width of the SCR.  
The capacitance then becomes  


With A = area of the capacitor plates, Q = charge on the plates and U = potential difference between the plates.  
The charge on the plates is equal to the number of ionized donors in the volume of the SCR. The volume is d · A and the number of charges is just the concentration of donors N_{D} (assuming that all are ionized) times the elementary charge e times the volume d · A, so we have  


Substituting this in the equation from above we obtain  


This gives us one of the more important semiconductors device equations in its simplest form  and this is the correct equation despite the somewhat questionable assumption of d_{cap} = d/2.  


The voltage U is of course the potential difference of the extreme values of the builtin potential which, in the case of the direct contact, is simply the difference of the Fermi energies expressed as potential, i.e.  


We immediately can generalize: If, in
addition to the "builtin" potential DE_{F}/e an additional external
potential U_{ex} is added from the outside by simply
connecting the material to a voltage source at U_{ex},
the total voltage becomes U = DE_{F}/e + U_{ex} and the width of the space charge region is 



It is easy to to obtain the same equation by integrating the Poisson equation for the case. This is done in an illustration module.  
This example illustrates nicely the approach we take in this chapter: We start from the most simple consideration of the case and try to deduce proper relations and formula by analogies  cutting corners a little if necessary (but only as long the results are still correct).  
"Ideal" pnJunction  
We now construct a pnjunction exactly along the recipe given above.  
Draw the band diagrams of both parts  
Join the two parts, move electrons to the materials with the lower Fermi energy, holes opposite  
Built up space charges and shift the potentials accordingly until the Fermi energy is constant everywhere.  
These steps are illustrates below:  


As a graphical aid, which will be is useful in cases to come, the carriers are schematically indicated as circles (electrons) and squares (holes). Many symbols indicate majority carriers, a few ones the minorities.  
The only differences to the first situation is that we now have a space charge region on both sides of the junction.  
The field lines are now pointing from the positively charged donor ions on the ntype side to the negatively charged acceptor ions on the pdoped side.  
The width of the space charge region is now a little more involved to calculate (but there is nothing new); it comes out to  


Now lets look at the various currents flowing in the conductance and valence bands without an external voltage.  
We know that the net current is zero  we are in an equilibrium condition as long as we do not apply an external voltage.  
We also know that we have a dynamic equilibrium as in the case of the recombination/generation business before. The net current is zero because the local currents cancel each other. This implies that the electron current flowing uphill (from left to right) must be identical in magnitude and opposite in sign to the one flowing from right to left (downhill).  
The same reasoning applies, of course, to the holes in the valence band.  
The partial currents discerned above have several specific names. The current component flowing uphill in energy is called:  
Diffusion current, because the driving force behind this current is the concentration gradient in the carrier density. This always leads to a current component given by Fick`s first law to  


With n = concentration of the carrier in question.  
It is also alternatively called recombination current because all the electrons (or holes) flowing into the other side become excess minority carriers there and must disappear by recombination, which can be depicted as a current flowing between the bands.  
Looking a little ahead, a pnjunction is a diode and currents in diodes are classified as forward or reverse currents. Well, the current component in question here, is responsible for the forward current in the diode and therefore is also addressed under that name. We will use mostly this name and abbreviate this current component with j_{F}  
The partial current flowing downhill in energy is called.  
Field current, because it is the current that the electrical field in the junction produces; i.e. the carriers flow in the general direction of the field lines with the respective proper signs. The diffusion current, in contrast, flows against the force exerted by the field (which will slow down these carriers!)  
Drift current, because it is the current that results from a drift  caused by the electical field  superimposed on random diffusion movements.  
Generation current, because the (minority) carriers that were swept down the energy hill (or up in the case of the holes) must be replaced by increased generation to keep the concentration constant.  
Reverse current in the diode nomenclature explained above. We will use mostly this name and abbreviate this current component with j_{R}.  
Simple CurrentVoltageCharacteristics  
In equilibrium, without an external voltage U_{ex}, we know that the net current is zero, or  
j_{F} = – j_{R}, or, to be more precise,  


To make life a little easier, we now drop some matterofcourse indices, and the signs; i.e. we only look at the magnitudes of the current components. It is easy enough to sort out the signs in the end again; in case of doubt refer to the link. In this shorthand we have  


If we draw these currents schematically into the banddiagram from above, it looks like this:  


Of course, the currents do not flow on both sides of the band edge; this is simply a drawing device.  
What happens for finite external voltages? First lets look at the band diagrams:  
An external potential eU is added which will raise or lower the equilibrium potential, depending on its sign. For sake of simplicity we only move the pside band diagram. It goes up for the negative pole of the voltage supply on the pside (always think about if electrons are repelled or attracted if you are unsure about how a potential moves bands), and down for the positive pole on the pside  
We no longer have an equilibrium situation  the Fermi energy is no longer constant everywhere; we must leave it undefined across the junction  
Far away from the junction, however, nothing (or very little) has changed. We still may consider these parts of the semiconductor to be in equilibrium or at least very close to it.  
The band diagram for the two possible basic cases then look like this:  


The two types of currents are shown increased (thicker arrow) if the energy barrier was lowered, and decreased if it was raised.  
The situation now is rather simple. The potential step is either increased or decreased. Lets first look what happens to the forward currents j_{F}(U).  
At zero volts the electron and hole forward currents have a certain value that is certainly determined by the height of the energy barrier that the carriers have to overcome, following Boltzmann statistics (as an approximation to the Fermi statistics, of course).  
In other words, the equation for this current includes an expE/kT term. Changing the energy barrier E by DE simply means to multiply the current at zero volts with exp –DE/kT.  
Since the magnitude of j_{F} at zero Volts external voltage is just j_{R}(U = 0); the forward current current j_{F}(U) at any voltage U must be  


and this is true for the electron and for the hole forward current.  
Imagine this as a lot of (drunken) bicyclists with various random momentums driving around randomly at the foot of a hill. Some of them on occasion will make it up the hill because their momentum was large enough and they were heading in the right direction. The fraction of bicyclist making it will simple change exponentially with the Boltzmann factor relative to their "current" at some reference value if the hill is raised or lowered.  
Now to the reverse current j_{R}(U)  
It corresponds to (drunken = randomly moving) bicyclists that drive around for a certain time (corresponding to the life time of the minority carriers) on the plateau on top of the hill before falling off their bikes (recombining).  
However, everybody who by accident makes it to the edge of the hill, will invariably careen down, i.e. produce a reverse current.  
Clearly, it only matters how many carriers happen to make it to the edge of the potential drop, not how deep it is. In other words: The reverse current does not depend on the external voltage or  


The total current is simply the difference between forward and reverse current for the electrons and the holes so we have 

This is the famous diode equation  and this is all there is to it for straightforward pnjunctions.  
Note that we did not assume that the forward or reverse current of the holes must be identical to the forward or reverse current of the electrons, respectively. Of course, if everything is symmetrical, we would have j_{R}^{e} = j_{R}^{h}, but we want to keep it a as general as possible even at that level since many real devices employ wildly different electron and hole currents across the junction.  
All that is left to do is to consider j_{R} a bit more closely.  
Thinking about drunken bicyclists, we might be tempted to assume that j_{R} should be proportional to their numbers, i.e. to the minority carrier density on the plateau.  
This, however, is wrong.  
So lets sober up and think a bit harder: You only can extract the bicyclists once! If you want a constant current over time, the best you can do is to take all carriers for the current that are generated per time unit and make it to the edge.  
In other words, you need to refill the ranks of bicyclists and the current will be proportional to the generation rate G (to what comes out of the bars per time interval), which we know is equal to the recombination rate R in undisturbed semiconductors and given by  


With t = lifetime. 
Thinking a bit harder yet, we realize that minority carriers generated way back from the junctions will not contribute to the current. They will fall off their bike (recombine) long before the have a chance to come close to the dropoff. Obviously we only must consider carriers within a certain length of the junction and this length is, of course, the diffusion length L.  
This gives us  


The elementary charge e is needed to make an electrical current out of a particle current. And as it turns out by more involved calculations, the proportionality constant is = 1.  
This gives us the complete diode equation exclusively in terms of primary materials properties: 

This is a remarkable achievement  obtained without involved calculations and cutting corners only once (proportionality const. = 1). But how good is it? Only the experiment can tell.  
If we measure the currentvoltage characteristics of an "ideal" pnjunction, we will find the following curves  


Generally, for Ge (or other semiconductors with relatively small band gaps) the measured characteristics is remarkably close to the one predicted by our formula. For Si, however (and other semiconductors with large band gaps), it is not a good formula, particularly for for the reverse current. We have large deviations from theory, labeled with black lettering. Lets see what went wrong (more details in the link):  
First, our theory has the usual (trivial) omissions. We did not include any ohmic resistance which can be easily added by putting a resistor in series to the junction. The result is the ohmic behavior for larger voltages as seen at larger currents.  
Second, everything will break down at high field strength; this is true for a junction, too. So for large reverse voltages (easily in the range 100V  1000V), the junction will go up in smoke while drawing a large current called "junction breakdown".  
While these points would apply to a Ge junction too (they are not shown in the ideal characteristics), the remaining deviations for Si involve a major oversight in our present theory:  
Third: We did not include carrier generation (and recombination) in the space charge region!  
In the bicyclist picture, we did not take into account that there are bars along the slope of the hill, too, which will emit bicyclists with a certain momentum and direction  they may either go up or down the hill and thus add to the current of particles moving in either direction.  
This adds four more current components (forward and reverse for holes and electrons) summarily called generation currents from the SCR.  
How large are these SCR caused current components?  
The answer comes from one of the more involved problems in semiconductor physics, it is not easy to obtain for real semiconductors (we will do it later). However, there is an easy way of thinking about it that even comes up with the usually given formula resulting from serious (but still approximate) computing. But we sure will have to cut a few corners!  
Here we go:  
CurrentVoltageCharacteristics with Generation Currents from the Space Charge Region  
We know the maximum current j_{max} that could emerge from the space charge region: It is the generation rate of carriers times the width of the SCR in complete analogy to the discussion above. More than that cannot flow out (in one direction for the maximum) per time unit.  
Every generation event produces a hole and an electron, so we have  


With d = width of the SCR and G_{SCR} = generation rate inside the space charge region.  
How large is G_{SCR}? We cannot use the old equation G = n_{min}/t because n_{min} is not constant across the SCR; it rather must look very schematically somewhat like this:  


This makes G_{SCR} a strong function of x  how are we going to handle this?  
Well, lets take a kind of average value for the carrier density, and what suggests itself is the intrinsic carrier density n_{i} which must be the value at the point where the two curves cross each other because of the mass action law stating n_{e} · n_{h} = n_{i}^{2}.  
Within this (questionable) approximation the maximum current generated in the SCR then becomes  


We know more. If the external voltage is zero, the total current is zero and that means that half of the SCR current must be forward and the other half reverse. We have  


If we now change the barrier height by eU, the forward current will change as before. However, we cannot simply multiply by exp –(eU/kT) as before!  
Whereas a carrier generated at the bottom of the hill experiences the full added potential, a carrier generated further up sees less or even no potential if it originates all the way uphill.  
So again, lets be sloppy and assume an average additional energy barrier, average between everything and nothing  and this will be eU/2.  
Again assuming that j_{R}(U) does not depend on the barrier height, but somewhat on U because the width d(U) of the SCR is voltage dependent, this gives us  


The two components no longer add up to j_{max}, but we don´t have to worry about this. We only would be very wrong for large forward currents, but in this case the bulk forward current is always much larger anyway  so it does not really matter much for the diode behavior.  
The total current from the space charge region then becomes j_{SCR}(U) = j_{F}(U) – j_{R}(U), and written out we have  


This happens to be exactly the same formula (give or take a factor of 2) that we would obtain with the "proper" theory. 
We now can write down the diode equation in all its splendor:  

Lets see what it means in forward direction:  
We may neglect the –1 in the SCR part of the forward current; it then adds a component that increases with exp(eU/2kT) (for neg. U), i.e. with half the slope of the bulk current (in an Arrhenius diagram). The halfslope component will always "win" at small voltages but pale to insignificance at higher voltages as shown in the illustration  


The combined characteristics looks very much like the measured behavior shown above (The sharp drop of the current close to U = 0 V is due to the factor –j_{R} in the diode equation which we neglect for larger voltages).  
We also see that the exact value of the SCR forward current indeed only matters for small values, as claimed above.  
What do we get in reverse directions?  
First, the reverse current now is voltage dependent because the width of the space charge region and thus j_{R} increases with a U^{1/2} law.  
Second, the total reverse current now is larger. Assuming a symmetric junction (N_{D} = N_{A} = N_{Dop}) and identical life times, and so on, for electrons and holes, it is easy to calculate the relation j_{R}(bulk)/j_{R}(SCR); we have  


The decisive factor is n_{i}. It decreases exponentially with increasing band gap E_{g}.  
This answers the question why Ge junctions follow the simple theory, while Si junctions are far off: If n_{i} >> N_{Dop}, j_{R}(bulk) >> j_{R}(SCR) and the SCR contribution will not be felt.  
The generation current from the SCR thus is much more important in semiconductors with larger band gaps. The characteristics from above show this rather clearly.  
Whereas the SCR part may be safely neglected for Ge (E_{g} = 0,6 eV), it is about (10^{2} – 10^{3}) times larger than the bulk diffusion current in Si.  
The SCR currents should be absolutely dominating in large bandgap semiconductors. Not only is n_{i} rather small, but t is very small, too, since these materials are often direct semiconductors. 
© H. Föll (Semiconductor  Script)