Microsegregation and "Current Burst" Theory
|Why Electrochemistry of Silicon May Help to Understand Wootz Steel|
|Take a piece of single crystalline silicon. Contact it on the backside, put the sample in a beaker containing some suitable electrolyte; diluted hydrofluoric acid would be best. Put some noble metal wire in the beaker, without it touching the Si sample. Platinum (Pt ) is best. Now apply some voltage to the system (a few volts will be enough) by hooking up the contacted Si sample to the positive pole of a battery or power supply, and the noble metal to the minus pole.|
|Just to be on the safe side: hydrofluoric acid (HF) would be your best choice if you plan to disfigure or to kill yourself in a particularly painful and messy way. It is an extremely dangerous chemical! Never ever get close to the stuff if you don't know exactly how to handle it!|
|OK, now that this is cleared up,
let's go on. You will find that some current will flow from the silicon into
the electrolyte and out again via the metal electrode, and that the silicon
will dissolve at a rate that is essentially
proportional to the current density (Ampères per cm2 sample
surface). Quite unexpectedly, it does so in rather peculiar ways. Let's look at
the basic processes for starters:
|This is very unusual behavior! Almost
any "Black box" with two wires coming out will not do that when
hooked up to a constant voltage. It may do nothing, explode, make noises, or
get hot but making the current oscillate it will not!
Note that the word "oscillations" means usually that something changes rhythmically in time. Now look at this:
|The inset show the distribution of
the current along some direction on the specimen surface. There is an obvious
two-dimensional current oscillation in
space, and since current dissolves the material, an array of deep
pores (about 300 µm here) is formed.
We are looking at self-organized current oscillations in space. Wherever current flows, the semiconductor dissolves, leaving an array of pores. In the picture it is indium phosphide (InP), but similar things happen in silicon and in many other semiconductors.
In other words: The formerly planar solid-liquid interface became unstable and is now "cellular". Or is it? Let's look at some cross-sections of those pores:
|Those are cross-sections for particularly well-expressed "dendritic" pores in silicon. In contrast, the interface going with the InP pores above would be cellular, indeed.|
|To be sure: dissolving silicon at room temperature in an electrochemical experiment is something very different from solidifying steel at very high temperatures. No doubt about that. However, there are obvious similarities. Indeed, on a more abstract level, both experiments have a lot in common. Let's see how that can be:|
both cases an energy current is driven
across a solid-liquid interface. During casting it is a heat current driven by
a temperature gradient, in the electrochemical experiment it is an electrical
current, driven by a gradient in the electrical potential. The basic equations
for these currents have the same mathematical structure, and one way the
systems copes with this occurs in both examples:
Increase the interface
area to get the current densities down
if you can't reduce the absolute current!
Now I give you the thought for your weekend. Can you guess what will happen if you reverse the process of solidification and start to melt a piece of iron? What would the solid-liquid interface look like? Would there be dendrites of liquid extending into the solid? Any other interface instabilities? Does anybody know? Or care?
|2. In both cases particle currents must flow towards, through, or away from the interface. For solidification this is described here, for the electrochemical experiment we need to bring the proper molecules to the interface so the necessary reactions can take place, and we need to get the reaction products away from the interface. In both cases diffusion and liquid flow are the means of transport, and once more it is the same math describing this.|
|3. Energy and particle currents need to be balanced for achieving steady state. You can't produce more oxide than you can dissolve, and you can't solidify more (alloy) melt (with equilibrium composition) than given by the transport of the right atoms to and from the interface.|
|4. Both systems are not in equilibrium. The larger the offset, the more drastic the actions to restore equilibrium. Both systems respond by changing the area of the solid-liquid interface and the interface velocity. We have, planar, cellular and dendritic crystal growth as well as dissolution.|
|5. Both system contain a stochastic component. Certain features can only be described by probabilities and not with fully deterministic equations. This induces a "chaotic" component in both systems and thus also the possibility to create order out of chaos by self-organization.|
|To be sure, there are specific
differences, too. Solidification generates heat, and that is an important
quantity since it interferes heavily with the heat transport and the
temperature gradients. Dissolution also generates heat but that is of minor
importance. Dissolution, while not directly generating an electrical current,
nevertheless interferes with the local potential gradient and the flow of the
electrical current in a subtle way.
In a nutshell, the electrochemical system does have close analogues to solidification topics like interface instabilities, cellular growth, dendritic growth and whatever produces quasi-periodic structures in space. In contrast to casting, it also produces easily measurable quasi-periodic structures in time that are well understood.
|I have claimed that striations are
rather universal and result from an interface that moves in a kind of
"stop-and-go" fashion. This is just a flashy expression for saying:
"the interface velocity oscillates in
I will now make a daring claim:
|There is a difference, however: For the electrochemical oscillations we have developed a detailed theory called "current burst" (CB) theory, whereas I'm not aware of a general "interface velocity oscillation" theory. We thus might profit from exploring possible analogies.|
|In what follows, I will first give
the basics of the current burst theory, and then draw the parallels to
interface velocity oscillations and striations.
Details on oscillations and pattern formation during the dissolution of semiconductors in general and silicon in particular can be found in the links
|The Current Burst Model|
|The easiest way to understand the essentials of the CB model is to get a (p-type) silicon specimen covered with a perfectly uniform oxide (SiO2) with a thickness of 50 nm or so. That is standard stuff in semiconductor technology, so the following experiment is easily done. Contact the backside of the sample, isolate backside and contact (cover it with wax, for example), put it into an electrolytic cell with some noble metal counter electrode and a fluoride bearing electrolyte, apply some voltage (about 5 V, + pole on the Si). and measure the current. It looks like that:|
|In the beginning of the experiment the current will be zero. That is not surprising because silicon dioxide is an extremely good electrical insulator, so no current can flow through the 50 nm thick layer. However, the electrolyte will slowly dissolve the SiO2 just as water dissolves salt. The SiO2 layer gets thinner and thinner, and the electrical field strength in the layer thus gets larger and larger - and something is bound to happen before it reaches infinity!|
|Before I get to that it is time to remember (or
learn) that voltage U and current I are completely
meaningless quantities from the viewpoint of materials! It is
electrical field strength and
current density that counts. I have
already cleared that up
with respect to the current density; it is simply the same thing with the field
strength. For our case the field strength E in the oxide layer is
| In our experiment the oxide thickness decreases
due to dissolution. The field strength then goes up, and for U=5
V reaches a value of about 10 MV/cm as soon as the oxide thickness
is down to 5 nm. An electrical field strength of 10 MV/cm is a
kind of "magical" number because it is about the highest field strength that the very best insulators
(like SiO2) can bear. Go beyond that field strength and
electrical breakdown or
electrical discharge will inevitably
occur in any material including vacuum.
You have seen and noticed electrical discharge taking place. When the field strength in the air gets too high, electrical discharge occurs in a spectacular way: thunderbolts have scared you and me, no doubt about that. Then you have literally seen but probably not noticed electrical discharge taking place when you turn on the light from a fluorescent tube. You start a (continuous) electrical discharge in there because a little starter device produces a high voltage for a few second when you press the button, and that initiates the discharge.
The two examples are perfect to elucidate two very special and very important aspects of all electrical discharge events - huge one like thunderbolts, or tiny ones on a nanometer scale in the SiO2 layer :
|We are done. The two points above embody the basic principles of the CB model. All we need to do is to apply it to our Si electrode in the experiment and write a little (actually a rather sophisticated and long) program to do the number crunching. The essential points for doing this are:|
|1. Derive two equations for the
probability Pstart(dOx) that
discharge starts or nucleates as as function of the oxide thickness
dOx, and a second equation for the probability
Pstop(dOx) that some
"burning" discharge stops as as function of the oxide thickness.
There is some leeway in choosing specific equations but no doubts about the general structure.
|2. Divide the specimen surface into small pixels. Assign an oxide thickness value to any pixel as a starting value. You can give any pixel the same value or anything you fancy; it doesn't matter.|
|3. Define the etch rate, i.e. how much oxide is dissolved per time increment. This depends essentially on the composition of the electrolyte and its temperature; the necessary relations are well-known.|
|4. If some current flows through the pixel let the oxide grow with a rate given by the current, and in the shape of a (more or less spherical) "bump" that spreads into neighboring pixels. The strength of the current is given by known external parameters.|
|Now start the calculations. Starting
at some time t0 the computer "looks" at
every pixel and notes the present oxide thickness. Then it looks at the two
|The system is now in a state that belongs to the
time t1=t0 + Dt. Dt
is the time increment that goes with the changes in oxide thickness.
The next few thousand steps in the calculations simply repeat the procedure above over and over again, keeping track of the parameters and plotting the result. This looks like this:
|The current oscillates! Everything
oscillates stochastically: things repeat
but never exactly as before.
Now why is that? There are two basic reasons for macroscopic oscillations to occur:
|1. We must have
local stochastic oscillators or things that
are on or off, growing fast or slow, awake or sleeping, very active or less
active - whatever. The only requirement is that there is a kind of recognizable
rhythm. In other words: We can define an average time for the duration of one cycle. For
example, assigning an average time of 24 hours to your waking/sleeping cycle
makes sense, but we cannot tell how long exactly your next cycle will be.
If the local oscillators do their thing without any regard to what their neighbors do, there will be no macroscopic oscillations. At any time there are - on average - equal numbers in the "on" or "off" (or sleeping / awake) state.
|2. We must have
some synchronization between the local
oscillators. This can happen by
With respect to your eating pattern, it is the interaction with your neighbors that tends to produce an oscillatory behavior with respect to the number of people being in an eating (or drinking) mode. There just aren't that many shapely secretaries in the cafeteria if you lunch at 3:30, and that's why you tend to lunch between 12:00 and 1:00. There is your interaction! My interaction is entirely different but the effect is the same. As long as there is any interaction, chances are that some synchronization will occur.
|The first ingredient is "automatically" present in the CB model, and so is the second one! There is a next-neighbor interaction in the model, and that produces synchronization. here is how:|
|Let's look schematically at a tiny part of the system in cross-section. It might look like this:|
|Current flow is indicated in red. Oxide dissolving during the time interval considered is shown in yellow (but not on the growing oxide bump for clarity). Note that the oxide bumps extend into the bulk silicon and into the electrolyte since oxidation increases the volume by a factor of two.|
|If we now move on a (few) time increments, CB 1 will become dormant since its oxide bump had almost reached a thickness were switching off will become very likely. In addition, a new CB (3) will have nucleated. This happens with high probability somewhere between the two old ones because there the oxide is thinnest.|
|Moving on a few more time increments, we reach the stage where CB 3 is just about to become dormant since its oxide bump has reached the thickness were switching off will become very likely; this is shown below|
|Did you notice the next-neighbor interaction that now will start to synchronize all those current bursts? No? Well - it is subtle but powerful:|
|Current burst No. 3 does not have to grow as much
oxide as its neighbors before it turns off since it "employs" the
still present oxide of its neighbors to get out of work earlier than it would
have if left to its own devices. Its switching off time thus is correlated to those of its neighbors, it is not what
it would have been without the crowd.
This is not yet synchronization but the beginning of it. If CBs are dense enough (i.e. the total current is high enough to space them at sufficiently high densities), interactions with the neighbors will rather quickly produce some degree of synchronization.
|To be sure, there are more mechanisms of
interactions than the one given above and they are contained in the full CB
model. Modelling by a "Monte Carlo" computer program has the big
advantage that all these effects come out automatically if one just describes
the basic processes correctly.
The problem with "Monte Carlo" programs is that they only can model a tiny part of the electrode surface since the number of pixels has to be small (a few millions) if you don't want to wait a long time for results. Moreover, the model might produce all kinds of unexpected results if you play with it, changing a parameter here and there.
|For example, in some computer runs the system produced structures like (shallow) pores! This was not expected but found to be another interaction feature that emerges under certain conditions. In a grand generalization the following statements result.|
|There are two basic kinds of interaction between
|There is something aesthetically pleasing about
that. If you can't feel that, send me an e-mail and climb back up your tree.
I'll send you a banana.
The full story is given in this reference.
|It only remains to look at synchronization induced from the outside. This is easily implemented into the model and works exactly as expected; consult the references for details. Especially interesting is the observation that rhythmic disturbances from the outside can induce system to develop oscillations that would not yet oscillate by themselves.|
|I only want to show one picture that demonstrates the effects of outside interference rather spectacularly:|
|All one needs to know is that the CB model
applies to the tip of those pores, where the dissolution takes place. CB's are
not synchronized in the left picture, and every now and then side pores are
In the right picture, synchronization was achieved by modulating the current with just the right frequency. Doing the experiment with frequencies different by more than about 20 % has no effect whatsoever. We might call that a stochastic resonance.
|Does a "Dendrite Burst" Model Explain Striations?|
|I wrote a
whole module arguing that
striations result if there is an "oscillating" solid liquid
interface. It is not so much the position in space that needs to oscillate but
the growth speed given by the average
thickness of the material that crystallizes per time unit.
Now let's compare essentials of the two processes: crystallization and electrochemical dissolution.
|The amount of material crystallizing
per time unit is essentially given by the rate of heat removal or the magnitude
of the energy current flowing through the
interface. It is just the opposite of the electrochemical experiment, where the
energy current (in the form of electrical current times voltage) determines the
amount of material dissolving per time unit. In both cases the currents can be
increased by increasing either the temperature gradient or the electrical
potential gradient right at the interface.
How large these gradients will be depends on how the various thermal or electrical resistances are switched in series between the extremes of temperature or electrical potential. In other words: it is the total thermal (electrical) resistance between the hottest (highest potential) point and the coldest (lowest potential) point. The interface resistance is just a part of this total resistance. In either case the gradient increases if the difference between the extremes increases. The difference between the extremes in the electrical potential we call "voltage", by the way.
|In both cases there is a intermediate layer
between the solid and the liquid. In the electrochemical experiment it is the
oxide layer. The nature of the intermediate layer is not quite so obvious for
casting or crystal growth, but there are several contenders:
|Dissolution and crystallization rates and morphologies depend heavily on the properties of these layers. In both cases the layers are subject to processes that remove them (oxide dissolution or diffusion / liquid flow / solidification between dendrites, ...) and processes that produce them (oxide formation or non-equilibrium solidification)|
|In the electrochemical dissolution
process, electrical breakdown supplies the mechanism for local stochastic
oscillators, and interaction between the oxide bumps or the local intermediate
layer non-uniformities, produce the synchronization.
If we could identify local stochastic oscillators and next neighbor interactions for solidification, the analogy would be complete and we could expect that self-organized synchronized interface velocity oscillations will occur under certain conditions.
|Well, there is at least one mechanism easy to conceive. All we need to assume is that the nucleation of a dendrite is a stochastic event, and that dendrites, after being nucleated, grow faster perpendicular to the interface for a while than the interface moves on average. What that implies is schematically pictured below.|
|The upper picture shows the usual steady-state model. Everything always looks the same as the interface moves upwards. The alternating black / grey layers symbolize the amount of solidified material after identical time steps.|
|The lower graphics illustrate a "dendrite burst" model. After nucleation, the dendrites grow faster than the rest, than the situation reverses. On average, exactly the same amount crystallizes as in the steady state model.|
|I will rest my case at this point. Note that I did not say that solidification proceeds always in a "dendrite burst model". Even if it does sometimes, it will not do it for all conditions. It may never do it because I might be simply wrong.|
|Be that as it may, I strongly believe (but don't know for sure) that there are some mechanisms, roughly following the general arguments given here, that can and will produce interface velocity oscillations under some solidification conditions.|
|1)||E. Foca, J. Carstensen, and H. Föll, "Modelling electrochemical current and potential oscillations at the Si electrode", J. Electroanal. Chem. 603, 175 (2007)|
|Link Hub: Segregation Science|
|Special Modules in Segregations Science:|
|1. Basics of Segregation|
|2. Constitutional Supercooling and Interface Stability|
|3. Supercooling and Microstructure|
|4. Segregation at High and Ambient Temperatures|
|Segregation in Silicon|
|Microsegregation and "Current Burst" theory This modul|
11.2.2 Metallurgy of Celtic Swords
Science of Alloying
11.5.2 Structure by Dendrites?
Segregation at Room Temperature
Segregation in Silicon
1. Basics of Segregation
Segregation at Room Temperature
Constitutional Supercooling and Interface Stability
© H. Föll (Iron, Steel and Swords script)