1.9 Thermodynamic Contacts: A system in thermal equilibrium


PIC

S2: The world, a heat bath, ...
Exchange of heat energy ΔQ

  • T1 = T2 = T

  • fixed volume V

  • fixed particle number N


Controlled by the system:
  • p: pressure

  • μ: chemical potential

  • S: entropy !!!


Examples:
  • many solids (V fixed)

  • gas in a fixed volume