Group 15 / VA; Nitrogen Group

Nitrogen (N) and phosphorous (P) are part of all biology and thus also of organic chemistry.
Phosphorous and arsenic (As) are very important for doping silicon, and nitrogen is found in many ceramics. There are also many applications of arsenic or its oxide (As2O3) in mystery books.
Bismuth is used in some high-tech products (like thermoelectric generators or Peltier elements): it's and antimony's (Sb) hey-days are yet to come.
Table of Basic Data
 
Name
(German)
Nitrogen
Stickstoff
Phosphorus
Phosphorus
Arsenic
Arsen
Antimony
Antimon
Bismuth
Bismut
Atomic number 7 15 33 51 83
Atomic mass [u] 14,01 30,97 74,92 121,75 208,98
Melting point [K] 63,29 317,3 sublimiert 903,89 544,5
Melting point [oC] -209,71 44,3 - 630,89 271,5
Melting point [oF]          
Boiling point [K] 77,4 553 886 2023 1833
Density [g/cm3] 1,17 1,82 5,72 6,69 9,80
Ionization energy [eV] 14,53 10,49 9,81 8,64 7,29
Electronegativitiy 3,1 2,1 2,2 1,8 1,7
Atomic radius [pm] 71 93 125 145 155
Ionic radius [pm] 171 44 69 89 96
Oxidation numbers 5, 4, 3, 2, -3 5, 3, -3 5, 3, -3 5, 3, -3 5, 3
Lattice typ
Transformation temp. [oC]
hcp
op
r
r
r
Lattice constant [Å]
(a or c)
? ? 4,14 4,50 4,74
Young's - Modul us [GPa] ? ? ? 54,9 31,9
Therm. expansion coefficient a
[10-6K-1]
? ? ? ? ?
 
In case of doubt all numbers are for room temperatures
fcc = face centered cubic; lattice const. = a
bcc = body centered cubic
sc = simple cubic
hp = simple hexagonal
hcp = hexagonal close packed; lattice constants a and c.
op = simple orthorhombic, monoclinic, triclinic
tp = simple tetragonal
dia = diamond structure
r = trigonal or rhomboedral trigonal


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© H. Föll (Iron, Steel and Swords script)