Group 14 / IVA; Carbon Group

This is the by far most important group. After all, you and me are carbon-based life forms. Without carbon (C) no biology, without silicon (Si) no Internet, electronics, computer tomography and so on.
I don't have to emphasize the importance of carbon -based organic chemistry, but let's not forget that the inorganic iron (Fe) based "chemistry" is still more important. Elementary clean carbon in the form of graphite is very important for parts of the high-tech industry, and elemental carbon in the form of diamonds are girl's best friends.
Dirty carbon in the form of coal, while killing the climate, is still indispensable for the wealth of nations.
Most of the silicon produced is not used for microelectronics or solar cells bit for steel making. A rather large part also goes into making silicones, oily or putty-like stuff, that does not only wonders to female profiles but is a high-tech material with rapidly growing applications.
And let's not forget that all glasses and a lot of ceramics contain large quantities of silicon.
Germanium (Ge) is used for some rather special applications an small quantities, but tin (Sn) and leaf (Pb) were and are metals of importance. Solder, a trivial but important part of all electronics, was a tin-lead alloy until recently. Since lead and many of its compounds are rather poisonous, lead is being phased out right now.
Tin was the essential alloy element for good bronze (a copper (Cu) tin (Sn) alloy). It was the essential strategic metal in the bronze age; mined in remote locations (like England) and traded across huge distances more than 3.000 years ago. In oxide (SnO2I is just about now starting a potentially big career as semiconductor.
Table of Basic Data.
 
Name
(German)
Carbon
Kohlenstoff
Silicon
Silicium
Germanium
Germanium
Tin
Zinn
Lead
Blei
Atomic number 6 14 32 50 82
Atomic mass [u] 12.01 28,09 72,61 118,71 207,2
Melting point [K] 3823 1683 1210,55 505,12 600,65
Melting point [oC] 3550 1410 937,55 232,12 327,65
Melting point [oF] 6422 2570 1719.5 450 622
Boiling point [K] 5100 2628 3103 2543 2013
Density [g/cm3] 3,51 2,33 5,32 7,29 11,34
Ionization energy [eV] 11,26 8,15 7,90 7,34 7,42
Electronegativitiy 2,5 1,7 2,0 1,7 1,6
Atomic radius [pm] 77,2 117 122,5 140,5 175,0
Ionic radius [pm] 16 26 53 93 132
Oxidation numbers 4, 2, -4 4, -4 4, 2 4, 2 4, 2
Lattice typ
Transformation temp. [oC]
dia
?
hcp
dia
dia
tp
13
dia
fcc
Lattice constant [Å]
(a or c)
?
?
5,43 5,66 5,82
3,18
4,95
Young's - Modul us [GPa] ? 13 ? 54,3 16,2
Therm. expansion coefficient a
[10-6K-1]
? ? ? ? 28
 
In case of doubt all numbers are for room temperatures
fcc = face centered cubic; lattice const. = a
bcc = body centered cubic
sc = simple cubic
hp = simple hexagonal
hcp = hexagonal close packed; lattice constants a and c.
op = simple orthorhombic, monoclinic, triclinic
tp = simple tetragonal
dia = diamond structure
r = trigonal or rhomboedral trigonal


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© H. Föll (Iron, Steel and Swords script)