2.4.4 Organic Semiconductors

This is were the action is - in 2007. Organic semiconductors are hot topics in R&D, and first products in the form of OLED's are on the market. RFID's may or may not follow soon.
Materials Science and technology for organic conductors and semiconductors is far from being well understood and there are major technological challenges, too. To give just one example: Oxygen, quite ubiquitous in air, is deadly for organic semiconductor devices. How can you keep a (cheap) device absolutely airtight for 20 years or so?
But first things first: What exactly are organic semiconductors?
There is no simple answer. Essentially you need two ingredients: Some organic molecule with a conjugated carbon-carbon chain. This means that there is a succession of "single bond - double bond", i.e. –C=C–C=C–C=C–C=C– with all kinds of stuff on the one remaining free valence of any C atom. There also must be some "doping" because the conjugated backbone chain of the polymer molecule is (surprisingly?!) not conductive or semi-conductive.
Doping is written in quotation marks because it has nothing to do with what we have learned about doping in Si - except that you add some impurities to your semiconductor.
We will come back to this topic later (if there is time). Meanwhile you may activate the folllwing links:


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© H. Föll (Semiconductor Technology - Script)