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For many mathematical problems, it is
far easier to use spherical coordinates instead of Cartesian ones. |
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In essence, a vector
r (we drop the underlining
here) with the Cartesian coordinates (x,y,z) is
expressed in spherical coordinates by giving its distance from the origin
(assumed to be identical for both systems) |r|, and the two
angles j and Q between the direction of r and the
x- and z-axis of the Cartesian system. |
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This sounds more complicated than it
actually is: j and Q are nothing but the geographic
longitude and
latitude. The picture below
illustrates this. |
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This is simple enough, for the
translation from one system to the other one we have the equations |
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| x = |
r · sinQ · cosj |
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r = |
(x2 + y2 +
z2)½ |
| y = |
r · sinQ · sinj |
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j = |
arctg (y/x) |
| z = |
r · cos Q |
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Q = |
arctg |
(x2 + y2 + z2
)½
z |
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Not particularly difficult, but not
so easy either. |
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Note that there is now a certain
ambiguity: You describe the same vector for
an ¥ set of values for Q and f, because you
always can add n·2p (n = 1,2,3...) to
any of the two angles and obtain the same result. |
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This has a first consequence if you
do an integration. Lets look at the ubiquitous case of normalizing a wave
function y (x,y,z) by demanding that |
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¥
ó
õ
¥ |
¥
ó
õ
¥ |
¥
ó
õ
¥ |
y (x,y,z) · dxdydz = 1 |
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In spherical coordinates, we
have |
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¥
ó
õ
0 |
2p
ó
õ
0 |
p
ó
õ
0 |
y (r,j,Q) · dr dj dQ = 1 |
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You no longer integrate from
-¥ to ¥ with respect to the angles, but from 0
to 2p for j
and from 0 to p for Q because this covers all of space. Notice the different upper bounds! |
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Lets try this by computing the volume
VR of a sphere with radius R. This is always done by
summing over all the differential volume elements dV inside the body
defined by some equation |
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In Cartesian coordinates we have for
the volume element dV = dxdydz, and for the integral:
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¥
ó
õ
¥ |
¥
ó
õ
¥ |
¥
ó
õ
¥ |
??? dxdydz |
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Well, if you can just formulate the integral, let alone solving it, you
are already doing well! |
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In spherical coordinates we first
have to define the volume element. This is relatively easily done by looking at
a drawing of it: |
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An incremental increase in the three
coordinates by dr, dj, and dQ produces the volume element dV which is close
enough to a rectangular body to render its volume as the product of the length
of the three sides. |
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Looking at the basic geometry, the length of the
three sides are identified as
dr, r · dQ, and r ·
sinQ · dj, which
gives the volume element |
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| dV |
= |
r2 · sinQ · dr ·
dQ · dj |
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The volume of our sphere thus results
from the integral |
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| Vr = |
¥
ó
õ
0 |
2p
ó
õ
0 |
p
ó
õ
0 |
r2 · sinQ · dr dj dQ = 2p · |
¥
ó
õ
0 |
p
ó
õ
0 |
r2 · sinQ · dr dQ = 2p |
· [cos p + cos 0] · |
¥
ó
õ
0 |
r2 · dr |
| Vr = |
2p · |
[2] · |
1/3R3 |
= (4/3) · p ·
R3 |
q.e.d. |
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Not extremely easy, but no problem
either. |
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Next, consider
differential
operators, like div, rot, or more general,
and
2
(= D). |
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Lets just look at D to see what happens. We have (for some function
U) |
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| Cartesian
coordinates |
| D = |
¶2U
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+ |
¶2U
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+ |
¶2U
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| ¶x2 |
¶y2 |
¶z2 |
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| Spherical
Coordinates |
| D = |
¶2U
¶r2 |
+ |
2
r |
· |
¶U
¶r |
+ |
1
r2 · sin2 · Q |
· |
¶2U
¶j2 |
+ |
1
r2 |
· |
¶2U
¶Q2 |
+ |
cotg Q
r2 |
· |
¶U
¶Q |
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Looks messy, OK, but it is
still a lot easier to work with this D
operator than with its Cartesian counterpart for problems with spherical
symmetry; witness the
solution of
Schrödingers equation for the Hydrogen atom. |
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Looking back now on our treatment of the
orientation polarization, we find yet another way of expressing spherical
coordinates for problems with particular symmetry: |
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We use a solid angle W
and its increment dW. |
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A
solid angle W is defined as the ratio of the area on a unit sphere
that is cut out by a cone with the solid angle W to the total surface of a unit sphere ( = 4pR2 = = 4p for
R = 1). |
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A solid angle of 4p therefore is the same as the total sphere, and a
solid angle of p is a cone with a (plane)
opening angle of 120o (figure that out our yourself). |
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An incremental change of a solid
angle creates a kind of ribbon around the opening of the cone defined by
W. This is shown below |
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Relations with spherical symmetry
where the value of Q does not matter - i.e.
it does not appear in the relevant equations - are more elegantly expressed
with the solid angle W. |
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That is the reason why practically all text books
introduce Q in the treatment of the
polarization orientation. And in order to be compatible with most text books,
that was what we did in the main part of the Hyperscript. |
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Of course, eventually, we have to replace
Q and dQ by
the basic variables that describe the problem, and that is only the angle
d in our problem (same thing as the angle
j here). |
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Expressing dQ in terms of d is
easy (compare the picture in
the main text) |
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The radius ot the circle bounded by the dQ ribbon is r·sind = sind because we have
the unit sphere, and its width is simply dd. |
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Its incremental area is thus the relation that we
used in the main
part. |
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© H. Föll (Electronic Materials - Script)