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There is not much to say about
conventional light sources like simple light bulbs, "halogen" light
bulbs, gas-discharge sources and so on. You all are quite familiar with them.
What follows gives the bare essentials. |
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Thomas Edison is usually credited as inventor of
the light bulb in 1880 but there were many others working on "light
bulbs" as early as 1840. Edison's breakthrough probably was due to
a combination of three factors: an effective incandescent material, a higher
vacuum compared to others, and a high resistance that made power distribution
at high voltages from a centralized source economically viable. |
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Consider a 100 W bulb operated at 230
V. It draws 0,44 A and thus has a resistance of 227
W. This is not easily achieved with the metal
wires then available. Edison of course, used carbon. It took until about
1905 before tungsten (W) filaments were used and until about
1913 before an inert gas like N2 was inside the bulb
instead of vacuum. |
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In fact, present day light bulbs are high-tech
objects despite their lowly image. If you have doubts about this consider: How
would you make a "coiled coil" filament as shown below for a standard
1 light bulb a from an extremely hard to shape material like
W in such a way that it is extremely cheap? |
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| Edisons light bulb |
Modern double coiled W filament |
| Source: Wikipedia |
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It is hard for us to imagine the
impact of "easy" light on humankind. Nevertheless, the 120+
years of illumination by incandescent
light has to come to an end right
now for reasons already
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Fluorescent and gas discharge light
sources have better efficiencies (and
efficacies) than
"black body radiators" but are not without problems of their
own. |
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The pictures tells it all, just look at the LED
branch. No more needs to be said about "conventional light
sources". |
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HID = "high intensity discharge" light
bulb;
the "Xenon" light in your more expensive car.
FL = "fluorescent light"
Hg = "mercury vapor lamp"
GL = "Glühlampe " (Glowing light); light bulb
LED = light emitting diode
Data from Osram |
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Light emitting diodes or
LED's nowadays come in
two variants: "Standard" LED's made from inorganic crystalline semiconductors based on, e.g.,
GAAlAs, GaP or GaN and "organic" LED's or
OLED's. |
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OLED devices are coming into
their own right now (2011). They are not yet mass products for general
lightning applications but we will find out how far they will go in the near
future (based on the work of possibly you and other materials scientists and
engineers; who else?). |
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Standard LED's have been around for more
than 40 years by now. However, they used to be only red in the beginning, see
the picture below, and their efficiencies were lousy. The breakthrough came
around 1990 when Shuji Nakamura of Nichia
Corporation almost single-handled introduced the GaN based blue
LED. This started the ongoing revolution of world wide lighting that
will contribute in a major way to saving the planet from the climate crisis. Of
course, if you google "Nakamura" you will find a soccer player
first. |
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The picture below gives an idea of
what was happening. Nobody seem to have updated this picture but the trends
continued. The LED market is growing rapidly |
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In analogy to "Moore's
law", "Haitz's Law" has been proposed: In every decade, the
cost per lumen (unit of useful light emitted) falls by a factor of 10,
the amount of light generated per LED package increases by a factor of
20, for a given wavelength (color) of light. Haitz also predicted that
the efficiency of LED-based lighting could reach 200 lm/W (lumen
per Watt) in 2020 crossing 100 lm/W in 2010. |
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This is
important: |
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More than 50% of the electricity consumption
for lighting or
20% of the totally consumed electrical energy
would be saved reaching 200 lm/W |
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So get going, young Material Scientist! |
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What does on need to do to make
better (and cheaper) LED's? |
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As a first step you must learn a minimum about
semiconductor physics or
Halbleiterphysik and
semiconductor technology. |
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The links provide starting points because
we are not going to do that here. |
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All the light sources discussed so
far share certain broad characteristics: |
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- They emit either a whole spectrum, i.e.
light with many colors, several spectral lines, or in the case of LED's
only one line but with a rather large half-width.
- Their light may come from a small area ("point source"; e.g.
standard LED), from a longish area ("fluorescent tubes") or even from
a large area (OLED's) and cannot really be processed into that parallel beam always used for illustrating optical
stuff
- The light is emitted in many directions
with various characteristics but never in
only one direction.
- The light is never fully coherent and mostly rather incoherent.
- The light is mostly not polarized
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Negate everything in that list
(except, maybe, polarization) and you have a Laser, a device that operates on the principle of
Light Amplification by Stimulated Emission of Radiation. |
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Lasers are rather recent light
sources; the first one was built by Maiman in 1960; for a short history use
the link |
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We cannot go much into the
principles of Lasers here. We only look at a few basic concepts and
keywords.. |
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The name "LASER" says it
all. To understand the very basic principles of Lasers, we look at a sequence
of a few simple pictures |
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First we need Light Amplification. For that we need a material with
two suitable energy levels, DE = hn apart. Light results whenever the electron jumps
from the higher level to the lower (ground) level one with a basic frequency of
n Hz. Note that this is not true for just any
levels; the electron may get rid of its energy in other ways, too, e.g. in
indirect semiconductors. |
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Second we need stimulated emission, a phenomenon that
was calculated and predicted by Albert Einstein in 1916. In simple terms,
stimulated emission means that a photon with the energy DE, when encountering an electron sitting on
the upper energy level, stimulates it to "fall down" and to emit a
photon that is identical in wave vector, and phase to the one that stimulates
the process (and does not get absorbed!) |
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Instead of one photon we have now two identical
one. We have achieved light
amplification. The two photons now stimulate other electrons along
their way to produce more photons, all being fully
coherent.. A lot of light now merges from the output. |
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The process from above, however, only
works once - until all electrons that happens to populate the upper energy
level are "down". |
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For a material with a dimension of
1 = 1 cm this takes about t = cmat
/l » [1/(2 · 109)] s =
0,5 ns, so we would have a rather short light flash. |
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For a "cw" or
continuous wave Laser we obviously
need to kick the electrons up to the higher energy level - just as fast as they
come down - by "pumping" the
Laser. In fact, we need to have more elctrons sitting at the high energy level
all the times than at the lower level. This is a very unusual state for
electrons called inversion. |
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Pumping
requires that we put plenty of energy into the system all the time. This can be
done by intense illumination (obviously with light of somewhat higher energy
than DE). Some Lasers of the US
military were supposed to be pumped by X-rays produced by a nuclear
explosion (no joke). They would not live long but still be able to produce a
short-lived ultra-high intensity Laser beam suitable for shooting down
missiles. |
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Our cheap, simple and long-lasting semiconductor
lasers, in contrast, are "simply" pumped by running a very large current density (> 1000
A/cm2) through a suitable pn-junction in some direct semiconductors.
This
link gives an idea of what that means. |
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Note that the incoming photon could just as well
kick a lower electron up, than it would be absorbed. The photon generated at
random some time later when the electron moves back down again is not adding to the desired output, it just adds
noise. |
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We are not done yet. The picture
above are greatly simplified because in reality we would produce light beams
running in all kinds of directions. That's not what we want. |
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Just as important, the energy of the light
produced would not be exactly DE but,
roughly, DE ± kT since our
excited electrons would also have some thermal energy. For a good monochromatic
light, an energy or frequency spread of about 1/40 eV at room
temperature is ridiculously large, so we must do something. |
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What we do is putting the pumped material inside
a "Fabry Perot" resonator.
This is nothing else but two mirrors (one with a reflectivity less than 100
%, i.e. "semi" transparent) that are exactly parallel (within
fractions of a µm) and at a distance L from each
other. |
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The light generated then is reflected back and
forth. For reasons clear to us now,
only waves with l = 2L/m; m =
1,2,3,... will
"fit". |
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A certain part of the light impinging on the
"semi" transparent mirror leaks out, forming our .now fully
monochromatic and coherent Laser beam.It propagates in one directiononly (here
perpendicular to the mirrors). |
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The way to visualize that is shown
here. |
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We have one standing wave right between the two
mirrors. Note that the wave length in the material is different from that in
air; you must take that into account when going through numbers. |
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Note that the picture for an organ pipe with an
acoustic wave inside would, in principlelook exactly the same. The pipe would
leak some of the wave and you hear a tone with a well defined frequency. |
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This looks pretty involved, so how come that we
have ultra-cheap Lasers in DVD drives? Because you don't need extra mirrors,
you just use the internal surface of your semiconductor single crystal that
reflect parts of the beam according to the Fresnel equations. If you obtain those surfaces by
cleaving down a low-index plane, they are automatically exactly plane parallel.
That makes Lasers more simple. |
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However, typically Lasers are far more
complicated than shown here. |
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An organ pipe or any longish musical
instrument will not only produce a tone with one frequency n0 but also the harmonics or overtones m
· n0. Same for our Laser, of
course, as shown below left. |
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A musical instrument that isn't long
and slender like an organ pipe or a flute (i.e. an essentially 1-dim. system)
but a rectangular box (or a complex-shaped body shape like a violin, can
contain standing waves in all directions with many possible wavelengths. Same
for our Laser; cf.. the situation in the figure on the upper right. |
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So depending on the exact shape of
the laser, the way it's pumped, and so on and so forth, there can be more than
just one Laser mode |
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We needed to get to that word. so let's repeat:
There can be more than just one standing wave inside a Laser resonator, or a
real laser might emit more than just one
mode. |
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We will not discuss what kinds of
Lasers we find for all kinds of applications here. There is a bewildering
variety and more and more different kinds are introduced. We just note one
important item: |
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Increasing the frequency / energy of Lasers
becomes "exponentially" difficult because with increasing photon
energy the number of ways it can be absorbed increases rapidly (there are lot
of empty states far above some densely populated ground level onto which
electrons could be "kicked") but only one state is useful for
lasing! |
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That's why there aren't so many UV Laser
around and no X-ray Lasers yet. |
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© H. Föll (Advanced Materials B, part 1 - script)